Several novel RAFT agents with pyrrolidone functionality and based on xanthates (RAFT agents 4 7) were synthesised to improve the RAFT polymerisation of “less activated” monomers (LAMs). Furthermore, multi armed RAFT agents (RAFT agents 9 11) based on xanthates were also synthesised with the aim of generating star like polymeric structures incorporating LAMs. 1H and 13C nuclear magnetic resonance (NMR) spectroscopy methods were used to characterise the RAFT agents synthesised.
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